I gave a short internal presentation @Vertigo last week about Commands in WPF. There's lot of information already on the web about this subject so I won't re-hash it here but instead link to the info instead.
Adam Nathan’s sample chapter on Important New Concepts in WPF: Commands
MSDN article: The Command Pattern In WPF
Keyvan Nayyeri: How to Add Commands to Custom WPF Control
Ian Griffiths: Avalon Input, Commands, and Handlers
Wikipedia: Command Pattern
MSDN Library: Commanding Overview
MSDN Library: CommandBinding Class
MSDN Library: Input and Commands How-to Topics
MSDN Library: EditingCommands Class
MSDN Library: MediaCommands Class
MSDN Library: ApplicationCommands Class
MSDN Library: NavigationCommands Class
MSDN Library: ComponentCommands Class
Also buried in the WPF SDK samples, there's a nice sample on RichTextBox editing which I've extended. You can find it here: RichTextEditor.zip